Occurrence, spatiotemporal trends, fate, and treatment technologies for microplastics and organic contaminants in biosolids: A review.

This review provides a comprehensive overview of the occurrence, fate, treatment and multi-criteria analysis of microplastics (MPs) and organic contaminants (OCs) in biosolids. A meta-analysis was complementarily analysed through the literature to map out the occurrence and fate of MPs and 10 different groups of OCs. The data demonstrate that MPs (54.7% occurrence rate) and linear alkylbenzene sulfonate surfactants (44.2% occurrence rate) account for the highest prevalence of contaminants in biosolids. In turn, dioxin, polychlorinated biphenyls (PCBs) and phosphorus flame retardants (PFRs) have the lowest rates (<0.01%). The occurrence of several OCs (e.g., dioxin, per- and polyfluoroalkyl substances, polycyclic aromatic hydrocarbons, pharmaceutical and personal care products, ultraviolet filters, phosphate flame retardants) in Europe appear at higher rates than in Asia and the Americas. However, MP concentrations in biosolids from Australia are reported to be 10 times higher than in America and Europe, which required more measurement data for in-depth analysis. Amongst the OC groups, brominated flame retardants exhibited exceptional sorption to biosolids with partitioning coefficients (log Kd) higher than 4. To remove these contaminants from biosolids, a wide range of technologies have been developed. Our multicriteria analysis shows that anaerobic digestion is the most mature and practical. Thermal treatment is a viable option; however, it still requires additional improvements in infrastructure, legislation, and public acceptance.

Characteristics of Microplastics and Their Affiliated PAHs in Surface Water in Ho Chi Minh City, Vietnam.

Microplastic pollution has become a worldwide concern. However, studies on the distribution of microplastics (MPs) from inland water to the ocean and their affiliated polycyclic aromatic hydrocarbons (PAHs) are still limited in Vietnam. In this study, we investigated the distribution of MPs and PAHs associated with MPs in canals, Saigon River, and Can Gio Sea. MPs were found at all sites, with the highest average abundance of MPs being 104.17 ± 162.44 pieces/m3 in canals, followed by 2.08 ± 2.22 pieces/m3 in the sea, and 0.60 ± 0.38 pieces/m3 in the river. Fragment, fiber, and granule were three common shapes, and each shape was dominant in one sampling area. White was the most common MP color at all sites. A total of 13 polymers and co-polymers were confirmed, and polyethylene, polypropylene, and ethylene-vinyl acetate were the three dominant polymers. The total concentration of MPs-affiliated PAHs ranged from 232.71 to 6448.66, from 30.94 to 8940.99, and from 432.95 to 3267.88 ng/g in Can Gio sea, canals, and Saigon River, respectively. Petrogenic sources were suggested as a major source of PAHs associated with MPs in Can Gio Sea, whereas those found in Saigon River and canals were from both petrogenic and pyrogenic sources.